If you want to do it a commercially sensible way , its too hard to do. Make it from thermal decomposition of carbonates (probably one of the easiest methods)
If you want to do it for a lab exercise it may be possible to fractionally distill at high pressure - look at phase diagrams of oxygen , nitrogen , argon & CO2 to see if possible
It you want to do it to mitigate CO2 induced global warming its not practical
hi my name is Alex & i think there are several ways to separate co2 from air
1)fractional distillation of liquid air
2)scrubbers that use a chemical that bonds to the co2 are used by submarines,at least one of these chemicals will release the co2 again when heated
freezing air which has had water vapour removed to a very low temp about -80c can make dry ice(solid carbon dioxide)
3)electrolysis
i`d like invite you to my website http://www.theworldwindow.net there many issues as Global Warming , The Contamination
Carbon sequestration
http://en.wikipedia.org/wiki/Carbon_sequ...
Carbon Dioxide Capture and Sequestration
http://www.epa.gov/climatechange/ccs/ind...
No way you can do it, the percentage of Co2 in the atmosphere is only 0.039% much too small without using advanced expensive technology.
Easiest way is to buy a canister of it
Keep on thinking. You will get there some day.
I want to store co2 in cylinders .